没有at morning之说,只有on morning. 固定搭配 on Sunday morning,表示 时间,比如 I usually go shopping on Sunday morning. 介词at 一般指在某个地方,或者指某一特定时间段。例句: I was cooking by the time you was knocking at the door.(at the door)
I went to post office at 4pm yesterday afternoon.(at 4pm)